Sorry to hear you cannot get the comms working between MonkeySqueeze and the QNAP NAS.
We would like MonkeySqueeze to work with all variations of the Squeezebox system, however we can can only program and test with the equipment we have. With respect to NAS equipment that is ReadyNAS and Synology devices. If anyone has a different NAS device and knows a little of VBscript programming then we would love them to do some testing for us. Post us in MonkeySqueeze Development and we will take it from there. viewtopic.php?f=19&t=59907
As explained in my previous post, the PC version can interface MediaMonkey with the Squeezebox system via MonkeySqueeze. If you're using MediaMonkey then the PC will be on, so this does work well in the short term.
Call back from time to time or better still become a follower of MonkeySqueeze on twitter and you will receive notifications of changes to the program.
Thanks for letting us know how you got on
P.S. If you have another NAS brand and you have successfully got it working with MonkeySqueeze then we would like you to post your settings so other users can use them.