I just got it working.

I uninstalled MMW completely (including Appdata folder[except for mm.db]) and removed all my MMW firewall rules (allowing access) from the registry.
I also uninstalled MMA and rebooted the PC and phone. Reinstalled everything and it worked.

The world may never know exactly what it was, but it had to be either some bug in the app data folder or in my firewall.

Help... Please?

MMA is always "searching" for a server whenever I try to sync.

MMW Media Sharing is enabled and the library is detectable on my Smart TV and Playstation.

I can EVEN access the library on another DLNA Android app called Media House.

I've tried reinstalling the app and rebooting several times with no success.

I've checked other threads and haven't found anything helpful yet.
Could I be missing something?

Phone: Samsung Galaxy S2 (T989 unrooted) Android: 4.0.3
MMA build148
MMW 4.1.0.1646